発表者名 |
黒田 清太 |
指導教員名 |
長谷川 達生 教授 |
発表題目(英語) |
Emergence and Control of Polar Crystal Structures in Layered Organic Semiconductors by the Effect of Molecular Mixing |
要旨(英語) |
Many organic semiconductor molecules with π-electron backbones that are asymmetrically substituted with alkyl chains exhibit remarkably high layered crystallinity, allowing the construction of single-crystal thin films through solution coating. Recently, the emergence of polar crystal structures has been reported in these layered organic semiconductors, where the molecules, lacking a center of symmetry, are all stacked in the same direction. Such polar organic semiconductors are expected to give rise to new device functionalities that utilize polarity, such as piezoelectric effects, electro-optic effects, and bulk photovoltaic effects. However, the types of molecular species that adopt polar crystal structures remain limited, and clear design guidelines for imparting strong polarity to materials have yet to be established. In this study, we discovered that the emergence and control of polar crystal structures can be achieved by mixing similarly shaped highly polar molecules.
In this presentation, I will introduce the results of XRD(X-ray diffraction), SHG (Second Harmonic Generation) measurements, and electro-optic effect measurements. |
発表言語 |
日本語 |